畢業(yè)設(shè)計(jì)說(shuō)明書(shū)中文摘要

本文通過(guò)細(xì)乳液聚合法，成功地制備了彩色墨粉用PYl7/PE蠟/電荷調(diào)節(jié)劑/苯丙樹(shù)脂四元復(fù)合乳膠粒子。實(shí)驗(yàn)對(duì)乳化工藝進(jìn)行優(yōu)化，并采用透射電子顯微鏡（TEM）、激光粒度分析儀、熱重分析儀（TG）等對(duì)樣品的形貌、粒度分布、熱性能等進(jìn)行了表征。研究了乳化劑的用量、蠟的用量、乳化轉(zhuǎn)速的選擇、引發(fā)劑的種類等對(duì)產(chǎn)品性能的影響。透射電鏡圖表明細(xì)乳液聚合法成功地將多組分包覆于樹(shù)脂基體內(nèi)。隨著乳化劑的用量增多，會(huì)使乳膠粒子粒徑減小。蠟的用量對(duì)乳膠粒子粒徑影響不大，但過(guò)多會(huì)降低乳液穩(wěn)定性。隨著乳化速度的加快，乳膠粒子的平均粒徑稍有下降，乳化速度過(guò)慢或過(guò)快都會(huì)降低乳液穩(wěn)定性。

關(guān)鍵詞  細(xì)乳液聚合，多組分復(fù)合，PY17，納米粒子，核殼結(jié)構(gòu)

畢業(yè)設(shè)計(jì)說(shuō)明書(shū)外文摘要

Title   Research on the Preparation of Multicomponent     

 Nano Composite Latex Particles Used as Color Toner

Abstract

In this paper PYl7/ PE wax/styrene acrylic resin composite latex particles were prepared successfully by the mini-emulsion polymerization. The emulsification process was optimized. The particle size and the particle distribution of composite latex particles were measured by the particle size analyzer respectively, the morphology of the latex particles was studied by transmission electron microscopy (TEM), and the thermal properties of the composite latex particles were analyzed by thermal gravimetric analyzer (TG). The effects of the amount of emulsifier, the quantity of wax, the emulsification speed and the choice of initiator species on the products were studied. The SEM results indicate that the multicomponent component were successfully encapsulated in the polymeric resin matrix using the emulsion polymerization. With the increase of the amount of emulsifier, the size of the latex particles will decrease. The amount of wax has little effect on the size of latex particles, but too much will decrease the stability of latex. The average size of latex particles will decrease slightly with the speed of emulsification, and the emulsion stability can decrease when the speed is too slow or too fast.

Keywords  Mini-emulsion polymerization，Multicomponent composite，PYl7，Nanoparticles，Core-Shell structure

 

目   次

1  緒論 1

1.1  課題背景 1

1.2  彩色墨粉組成組分 1

1.2.1  樹(shù)脂組分 1

1.2.2  顏料組分 1

1.2.3  蠟組分 2

1.2.4  電荷調(diào)節(jié)劑組分 2

1.3  彩色墨粉制備方法 2

1.3.1  溶劑法 2

1.3.2  熔融粉碎法 2

1.3.3  懸浮聚合法 3

1.3.4  乳液聚合法 3

1.3.5  細(xì)乳液聚合法 3

1.4  彩色墨粉生產(chǎn)及應(yīng)用現(xiàn)狀 4

1.4.1  彩色墨粉國(guó)內(nèi)外發(fā)展?fàn)顩r 4

1.4.2  彩色墨粉制備技術(shù)及研究展望 5

1.5  本課題研究?jī)?nèi)容 5

2  實(shí)驗(yàn)部分 7

2.1  實(shí)驗(yàn)原料與儀器 7

2.2  實(shí)驗(yàn)工藝 8

2.2.1  原料提純 8

2.2.2  實(shí)驗(yàn)方案及流程 8

2.2.3  樣品測(cè)試與表征 9

2.3  結(jié)果與討論 10

2.3.1  水相與油相的混合方式 10

2.3.2 CCA的分散方式 10

2.3.3  乳化劑用量對(duì)復(fù)合乳膠粒子粒徑及分散性的影響 11

2.3.4  PE蠟用量對(duì)復(fù)合乳膠粒子粒徑及分散性的影響 12

2.3.5  PE蠟對(duì)復(fù)合乳膠粒子熱性能的影響 13

2.3.6  乳化速度對(duì)復(fù)合乳膠粒子粒徑及分散性的影響 14

2.3.7  引發(fā)劑種類的影響 14

結(jié)  論 16

致  謝 18

參 考 文 獻(xiàn) 19